Three polymorphs of one luminogen: how the molecular packing affects the RTP and AIE properties?

Author:

Yang Jie12345,Ren Zichun12345,Chen Bin6785,Fang Manman12345,Zhao Zujin6785ORCID,Tang Ben Zhong6785,Peng Qian91011125,Li Zhen12345ORCID

Affiliation:

1. Department of Chemistry

2. Hubei Key Lab on Organic and Polymeric Opto-Electronic Materials

3. Wuhan University

4. Wuhan 430072

5. China

6. State Key Laboratory of Luminescent Materials and Devices

7. South China University of Technology

8. Guangzhou 510640

9. Key Laboratory of Organic Solids

10. Beijing National Laboratory for Molecular Science (BNLMS)

11. Institute of Chemistry Chinese Academy of Sciences

12. 100190 Beijing

Abstract

Three crystalline polymorphs of CzS-CN, which display much different properties of room temperature phosphorescence (RTP) and aggregation-induced emission (AIE), are reported.

Funder

South China University of Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Reference42 articles.

1. J. B. Birks , Photophysics of Aromatic Molecules, Wiley, London, 1970

2. B. Valeur , Molecular Fluorescence: Principle and Applications, Wiley, Weinheim, 2005

3. Organic Single Crystals: An Essential Step to New Physics and Higher Performances of Optoelectronic Devices

4. Organic Donor–Acceptor Complexes as Novel Organic Semiconductors

5. Synthesis of borophenes: Anisotropic, two-dimensional boron polymorphs

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