1,2,3-Triazolyl bisphosphine with pyridyl functionality: synthesis, copper(<scp>i</scp>) chemistry and application in click catalysis-Reference-Cited by-同舟云学术

1,2,3-Triazolyl bisphosphine with pyridyl functionality: synthesis, copper(i) chemistry and application in click catalysis

Published:2023 Issue:28 Volume:47 Page:13538-13546
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Sheokand Sonu¹^ORCID,Mohite Manali A.¹,Mondal Dipanjan¹,Rangarajan Shalini¹,Balakrishna Maravanji S.¹^ORCID

Affiliation:

1. Phosphorus Laboratory, Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400076, India

Abstract

This paper describes the synthesis, copper chemistry and catalytic applications of copper(i) complexes, containing 1,2,3-triazolyl-bisphosphine with a pyridine moiety, in 1,3-dipolar cycloaddition reactions and one-pot triazole synthesis.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NJ/D3NJ01445B

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1. Ru^II complexes of 1,2,3-triazole appended tertiary phosphines, [P(Ph){(o-C₆H₄)(1,2,3-N₃C(Ph)CH}₂] and [P(Ph){o-C₆H₄(CCH)-(1,2,3-N₃-Ph)}₂]: highly active catalysts for transfer hydrogenation of carbonyl/nitro compounds and for α-alkylation of ketones

2. Transfer hydrogenation using recyclable polyurea-encapsulated palladium: efficient and chemoselective reduction of aryl ketones

3. Exclusively Ligand-Mediated Catalytic Dehydrogenation of Alcohols

4. Cobalt-Catalyzed α-Alkylation of Ketones with Primary Alcohols

5. Near-Ambient-Temperature Dehydrogenative Synthesis of the Amide Bond: Mechanistic Insight and Applications

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