Pressure-induced structural transformations and new polymorphs in BiVO4

Author:

Cheng Xuerui1234ORCID,Guan Jiwen5678,Jiang Liying9234,Zhang Huanjun1234,Wang Pan10678,Adeniyi Adebayo O.1112138,Yao Yansun1112138,Su Lei14154,Song Yang567810ORCID

Affiliation:

1. School of Physics and Electronic Engineering

2. Zhengzhou University of Light Industry

3. Zhengzhou

4. P. R. China

5. Department of Physics and Astronomy

6. University of Western Ontario

7. London

8. Canada

9. College of Electrical and Information Engineering

10. Department of Chemistry

11. Department of Physics and Engineering Physics

12. University of Saskatchewan

13. Saskatoon

14. Center for High Pressure Science and Technology Advanced Research

15. 100094 Beijing

Abstract

BiVO4 exhibits a rich structural polymorphism under high pressure where both fergusonite- and zircon-type BiVO4 transform to scheelite and β-fergusonite structures upon compression.

Funder

National Natural Science Foundation of China

Science and Technology Department of Henan Province

Henan University

Natural Sciences and Engineering Research Council of Canada

Canada Foundation for Innovation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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