Expedient alkyne semi-hydrogenation by using a bimetallic AgCu–C<sub>3</sub>N<sub>4</sub> single atom catalyst-Reference-Cited by-同舟云学术

Expedient alkyne semi-hydrogenation by using a bimetallic AgCu–C₃N₄ single atom catalyst

Published:2024 Issue:27 Volume:15 Page:10577-10584
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Song Jingting¹^ORCID,Cai Xiangbin²^ORCID,Chen Zhongxin³^ORCID,Wang Tie⁴^ORCID,Xi Shibo⁵,Hu Qikun¹^ORCID,Yan Ning⁴^ORCID,Loh Kian Ping¹^ORCID

Affiliation:

1. Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore

2. Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore

3. School of Science and Engineering, The Chinese University of Hong Kong, Shenzhen, Guangdong, 518172, China

4. Department of Chemical and Biomolecular Engineering, National University of Singapore, 117585, Singapore

5. Institute of Chemical and Engineering Sciences, Agency for Science, Technology, and Research (A*STAR), 1 Pesek Road, Jurong Island, Singapore 627833, Singapore

Abstract

This work presents a high-loading AgCu–C3N4 single atom catalyst for alkyne semi-hydrogenation, achieving superior activity and selectivity (99%) through cooperative Ag–Cu interactions at close inter-metal distances.

Funder

National University of Singapore

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC02469A

Reference38 articles.

1. Single-atom catalyst: a rising star for green synthesis of fine chemicals

2. Single-Atom Pd1/Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene

3. Hydride formation thermodynamics and hysteresis in individual Pd nanocrystals with different size and shape

4. Selective hydrogenation of 1,3-butadiene on platinum–copper alloys at the single-atom limit

5. Half-Sandwich Ruthenium Carbene Complexes Link trans-Hydrogenation and gem-Hydrogenation of Internal Alkynes

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