Vibrational energy relaxation dynamics of diatomic molecules inside superfluid helium nanodroplets. The case of the I2 molecule
Author:
Affiliation:
1. Departament de Ciència de Materials i Química Física and IQTC
2. Universitat de Barcelona
3. 08028 Barcelona
4. Spain
5. Departamento de Química Física Aplicada
6. Universidad Autónoma de Madrid
7. 28049 Cantoblanco
Abstract
The vibrational relaxation (VER) of a X2 molecule in a 4He superfluid nanodroplet (HeND; 0.37 K) was studied adapting a quantum approach recently proposed by us. In the first theoretical study on the VER of molecules inside HeND the I2 molecule was examined [cascade mechanism (ν → ν − 1; ν − 1 → ν − 2; …) and time scale of ns].
Funder
Ministerio de Ciencia e Innovación
Universitat de Barcelona
Generalitat de Catalunya
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CP/C7CP05694J
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3. Semiclassical Theory of Vibrational Energy Relaxation in the Condensed Phase
4. A. Nitzan , Chemical dynamics in condensed phases , Oxford University Press , Oxford , 2006
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