Mechanistic study on the reaction of pinB-BMes2 with alkynes based on experimental investigation and DFT calculations: gradual change of mechanism depending on the substituent-Reference-Cited by-同舟云学术

Mechanistic study on the reaction of pinB-BMes2 with alkynes based on experimental investigation and DFT calculations: gradual change of mechanism depending on the substituent

Published:2021 Issue:28 Volume:12 Page:9806-9815
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wu Linlin¹²³⁴^ORCID,Kojima Chiemi⁵⁶⁷⁸⁹,Lee Ka-Ho¹²³⁴^ORCID,Morisako Shogo¹⁰¹¹¹²¹³⁹^ORCID,Lin Zhenyang¹²³⁴^ORCID,Yamashita Makoto¹⁰¹¹¹²¹³⁹^ORCID

Affiliation:

1. Department of Chemistry

2. The Hong Kong University of Science and Technology

3. Kowloon

4. Hong Kong

5. Department of Applied Chemistry

6. Faculty of Science and Engineering

7. Chuo University

8. Tokyo 112-8551

9. Japan

10. Department of Molecular and Macromolecular Chemistry

11. Graduate School of Engineering

12. Nagoya University

13. Nagoya

Abstract

Combination of kinetic and DFT studies revealed a subtle balance for substituent effect toward the regioselectivity of the product in metal-free and base-catalyzed diboration of arylacetylenes.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Research Grants Council, University Grants Committee

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC02863D

Reference50 articles.

1. Synthesis of Organoboron Compounds via the Transition Metal-Catalyzed Addition and Coupling Reaction of (Alkoxo)diborons.

2. Chemistry of Group 13 element-transition metal linkage — the platinum- and palladium-catalyzed reactions of (alkoxo)diborons