Investigating pyridazine and phthalazine exchange in a series of iridium complexes in order to define their role in the catalytic transfer of magnetisation from para-hydrogen-Reference-Cited by-同舟云学术

Investigating pyridazine and phthalazine exchange in a series of iridium complexes in order to define their role in the catalytic transfer of magnetisation from para-hydrogen

Published:2015 Issue:7 Volume:6 Page:3981-3993
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Appleby Kate M.¹²³⁴⁵,Mewis Ryan E.¹²³⁴⁵,Olaru Alexandra M.¹²³⁴⁵,Green Gary G. R.¹²³⁴⁵,Fairlamb Ian J. S.⁶²⁴⁵,Duckett Simon B.¹²³⁴⁵

Affiliation:

1. Centre for Hyperpolarization in Magnetic Resonance

2. University of York

3. York Science Park

4. York

5. UK

6. Department of Chemistry

Abstract

Reaction of [Ir(IMes)(COD)Cl] with pyridazine (pdz) or phthalazine (phth) and H₂ results in the formation of the para-hydrogen magnetisation transfer catalysts [Ir(H)₂(IMes)(pdz)₃]Cl and [Ir(H)₂(IMes)(phth)₃]Cl.

Funder

Wellcome Trust

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC00756A

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