Au-iClick mirrors the mechanism of copper catalyzed azide–alkyne cycloaddition (CuAAC)-Reference-Cited by-同舟云学术

Au-iClick mirrors the mechanism of copper catalyzed azide–alkyne cycloaddition (CuAAC)

Published:2015 Issue:33 Volume:44 Page:14747-14752
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Powers Andrew R.¹²³⁴⁵,Ghiviriga Ion¹²³⁴⁵,Abboud Khalil A.¹²³⁴⁵,Veige Adam S.¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Center for Catalysis

3. University of Florida

4. Gainesville

5. USA

Abstract

Isolated digold-triazolate products and first-order kinetic profiles for Au–acetylide/azide reactants in iClick provide compelling support for two copper ions in CuAAC.

Funder

American Chemical Society Petroleum Research Fund

Division of Chemistry

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02405F

Reference46 articles.

1. 1,3-Dipolar cycloaddition between a metal–azide (Ph3PAuN3) and a metal–acetylide (Ph3PAuCCPh): an inorganic version of a click reaction

2. Click Chemistry: Diverse Chemical Function from a Few Good Reactions

3. Peptidotriazoles on Solid Phase: [1,2,3]-Triazoles by Regiospecific Copper(I)-Catalyzed 1,3-Dipolar Cycloadditions of Terminal Alkynes to Azides

4. A Stepwise Huisgen Cycloaddition Process: Copper(I)-Catalyzed Regioselective “Ligation” of Azides and Terminal Alkynes

5. Cycloaddition reactivity studies of first-row transition metal–azide complexes and alkynes: an inorganic click reaction for metalloenzyme inhibitor synthesis

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