Theory and quantitative assessment of pH-responsive polyzwitterion–polyelectrolyte complexation-Reference-Cited by-同舟云学术

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Theory and quantitative assessment of pH-responsive polyzwitterion–polyelectrolyte complexation

Published:2024 Issue: Volume: Page:
ISSN:1744-683X
Container-title:Soft Matter
language:en
Short-container-title:Soft Matter

Author:

Hoover Samuel C.¹,Margossian Khatcher O.²³^ORCID,Muthukumar Murugappan²^ORCID

Affiliation:

1. Department of Chemical Engineering, University of Massachusetts Amherst, Amherst, MA 01003, USA

2. Department of Polymer Science and Engineering, University of Massachusetts Amherst, Amherst, MA 01003, USA

3. Rush University Medical Center and John H. Stroger Hospital of Cook County, both in Chicago, IL 60612, USA

Abstract

We introduce a theoretical framework to describe the pH-sensitive phase behavior of polyzwitterion–polyelectrolyte complex coacervates that reasonably captures the phenomenon from recent experimental observations.

Funder

Air Force Office of Scientific Research

Division of Chemistry

Division of Materials Research

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SM/D4SM00575A

Reference73 articles.

1. Phase separation in polyelectrolyte solutions. Theory of complex coacervation

2. Entropy and enthalpy of polyelectrolyte complexation: Langevin dynamics simulations

3. Binodal Compositions of Polyelectrolyte Complexes

4. Ternary, Tunable Polyelectrolyte Complex Fluids Driven by Complex Coacervation

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