Catalyst-free cross-coupling of N-tosylhydrazones with chromium(0) Fischer carbene complexes: a new approach to diarylethanone-Reference-Cited by-同舟云学术

Catalyst-free cross-coupling of N-tosylhydrazones with chromium(0) Fischer carbene complexes: a new approach to diarylethanone

Published:2015 Issue:11 Volume:2 Page:1450-1456
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Hu Fangdong¹²³⁴⁵,Yang Jinghui¹²³⁴⁵,Xia Ying¹²³⁴⁵,Ma Chen⁶⁷⁸⁹,Xia Haiping¹⁰¹¹¹²⁹,Zhang Yan¹²³⁴⁵,Wang Jianbo¹²³⁴⁵

Affiliation:

1. Beijing National Laboratory of Molecular Sciences (BNLMS)

2. Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education

3. College of Chemistry

4. Peking University

5. Beijing 100871

6. School of Chemistry and Chemical Engineering

7. Shandong University

8. Jinan 250100

9. China

10. College of Chemistry and Chemical Engineering

11. Xiamen University

12. Xiamen

Abstract

Chromium Fischer carbene complexes react with the in situ generated diazo compounds to afford methyl enolate products which are hydrolyzed to give diarylethanones.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/QO/C5QO00241A

Reference61 articles.

1. Organic Synthesis with .alpha.-Diazo Carbonyl Compounds

2. M. P. Doyle , M. A.McKervey and T.Ye, Modern Catalytic Methods for Organic Synthesis with Diazo Compounds, Wiley, New York, 1998

3. Recent studies on the reactions of α-diazocarbonyl compounds

4. Modern Organic Synthesis with α-Diazocarbonyl Compounds

5. Recent Advances in Asymmetric Catalytic Metal Carbene Transformations

Cited by 23 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. N‐Tosylhydrazones as [N,N] Synthons in Heterocyclic Chemistry: Synthesis of 3,5‐Disubstituted N‐Alkenyl‐1H‐pyrazoles;Advanced Synthesis & Catalysis;2024-04-24

2. Stereoselective Synthesis of trans-Stilbenes through Silver-Catalyzed Self-Coupling of N-Triftosylhydrazones: An Experimental and Theoretical Study;Organic Letters;2023-05-10

3. Zn(II)-catalyzed Formal Cross-dimerization of Carbenes Using Acylsilanes and Diazo Esters;Chemistry Letters;2023-01-05

4. Synthesis of Olefins by Formal Carbene Coupling;Advanced Synthesis & Catalysis;2022-08-17

5. Regioselection in the synthesis of 4-benzyltetral-1-ones and the new 4-arylbenzosuber-1-ones;Tetrahedron;2021-04