Halogen molecular modifications at high pressure: the case of iodine

Author:

Shi Jingming12345ORCID,Fonda Emiliano678910ORCID,Botti Silvana1112131415ORCID,Marques Miguel A. L.1516171814ORCID,Shinmei Toru19202122ORCID,Irifune Tetsuo1920212223,Flank Anne-Marie678910,Lagarde Pierre678910,Polian Alain678910ORCID,Itié Jean-Paul678910ORCID,San-Miguel Alfonso12345ORCID

Affiliation:

1. Univ. Lyon

2. Université Claude Bernard Lyon 1

3. CNRS

4. Institut Lumière Matière

5. F-69622 Lyon

6. Synchrotron SOLEIL

7. L'Orme des Merisiers

8. Saint-Aubin

9. BP48

10. 91192 Gif-sur-Yvette Cedex

11. Institut für Festkörpertheorie und -Optik

12. Friedrich-Schiller-Universität Jena

13. 07743 Jena

14. Germany

15. European Theoretical Spectroscopy Facility

16. Institut für Physik

17. Martin-Luther-Universität Halle-Wittenberg

18. D-06099 Halle

19. Geodynamics Research Center

20. Ehime University

21. Matsuyama

22. Japan

23. Earth-Life Science Institute

Abstract

Using X-ray absorption spectroscopy and atomistic modeling, we demonstrate that in halogens, the formation of a connected molecular structure takes place at pressures well below metallization.

Funder

National Natural Science Foundation of China

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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