Selective monoallylation of anilines to <i>N</i>-allyl anilines using reusable zirconium dioxide supported tungsten oxide solid catalyst-Reference-Cited by-同舟云学术

Selective monoallylation of anilines to N-allyl anilines using reusable zirconium dioxide supported tungsten oxide solid catalyst

Published:2022 Issue:19 Volume:12 Page:11877-11884
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Kon Yoshihiro¹^ORCID,Tsurumi Shota¹,Yamada Shunsuke²,Yokoi Toshiyuki²,Fujitani Tadahiro¹^ORCID

Affiliation:

1. Interdisciplinary Research Center for Catalytic Chemistry, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan

2. Nanospace Catalysis Unit, Institute of Innovative Research, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan

Abstract

We present a 10 wt% WO3/ZrO2 catalyzed monoallylation reaction of anilines to give various N-allyl anilines in good yields. The developed catalytic reaction is applicable to the continuous flow synthesis of N-allyl aniline with 97% selectivity.

Funder

New Energy and Industrial Technology Development Organization

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RA/D2RA00198E

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