Ag(i) and Cu(i) cyclic-triimidazole coordination polymers: revealing different deactivation channels for multiple room temperature phosphorescences

Author:

Malpicci Daniele1234ORCID,Lucenti Elena534ORCID,Forni Alessandra534ORCID,Marinotto Daniele534ORCID,Previtali Andrea12345ORCID,Carlucci Lucia1234ORCID,Mercandelli Pierluigi1234ORCID,Botta Chiara534ORCID,Righetto Stefania1234,Cariati Elena12345ORCID

Affiliation:

1. Department of Chemistry

2. Università degli Studi di Milano and INSTM RU

3. 20133 Milano

4. Italy

5. Institute of Sciences and Chemical Technologies “Giulio Natta” (SCITEC) of CNR

Abstract

The photophysics of isostructural Ag(i) and Cu(i) 1D and 3D coordination polymers based on cyclic triimidazole reveals excitation wavelength-dependent multiple emissions with different radiative paths according to the coordinated metal.

Funder

Regione Lombardia

Fondazione Cariplo

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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