Strong polymer molecular weight-dependent material interactions: impact on the formation of the polymer/fullerene bulk heterojunction morphology

Author:

Kim Joo-Hyun1234ORCID,Gadisa Abay1234,Schaefer Charley567,Yao Huifeng89101112ORCID,Gautam Bhoj R.1234,Balar Nrup13234,Ghasemi Masoud1234,Constantinou Iordania14234,So Franky14234,O'Connor Brendan T.13234,Gundogdu Kenan1234,Hou Jianhui89101112ORCID,Ade Harald1234

Affiliation:

1. Department of Physics and ORaCEL

2. North Carolina State University

3. Raleigh

4. USA

5. Simbeyond B.V.

6. 5612 AE Eindhoven

7. The Netherlands

8. Beijing National Laboratory for Molecular Sciences

9. State Key Laboratory of Polymer Physics and Chemistry

10. Institute of Chemistry

11. Chinese Academy of Sciences

12. Beijing 100190

13. Department of Mechanical and Aerospace Engineering and ORaCEL

14. Department of Materials Science and Engineering and ORaCEL

Abstract

The morphological evolution is initiated by L–L or L–S phase separation (left) and further developed by molecular mobility, governed by polymer–solvent interactions which determine the final domain size of the BHJ layer (right).

Funder

U.S. Naval Research Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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