Probing the effect of metal to ligand charge transfer on the oxygen evolution reaction in Au incorporated Co(OH)<sub>2</sub> thin film electrocatalysts-Reference-Cited by-同舟云学术

Probing the effect of metal to ligand charge transfer on the oxygen evolution reaction in Au incorporated Co(OH)₂ thin film electrocatalysts

Published:2023 Issue:38 Volume:11 Page:20816-20823
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Kamar Rusha¹²,Agoston Roland¹,van Riessen Grant A.³,Hinsley Gerard⁴^ORCID,O'Mullane Anthony P.¹²^ORCID,Jones Michael W. M.¹²⁵^ORCID

Affiliation:

1. School of Chemistry and Physics, Queensland University of Technology (QUT), Brisbane, Queensland, Australia

2. Centre of Materials Science, Queensland University of Technology (QUT), Brisbane, Queensland, Australia

3. Department of Mathematical and Physical Sciences, School of Computing, Engineering and Mathematical Science, La Trobe University, Bundoora, Victoria 3086, Australia

4. Deutsches Elektronen Synchrotron DESY, Germany

5. Central Analytical Research Facility (CARF), Queensland University of Technology (QUT), Brisbane, Queensland, Australia

Abstract

Incorporating Au in small amounts reduces the metal-to-ligand charge transfer effect in Co(OH)2 electrocatalysts during the OER that aids the nucleophilic attack of OH− ions on adsorbed oxygen, easing its desorption from the catalyst surface.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/TA/D3TA03923D

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