Incorporation of a ruthenium–bis(pyridine)pyrazolate (Ru–bpp) water oxidation catalyst in a hexametallic macrocycle
Author:
Affiliation:
1. Institute of Chemical Research of Catalonia (ICIQ)
2. E-43007 Tarragona
3. Spain
4. Departament de Química
5. Universitat Autònoma de Barcelona
Abstract
New terpyridine-functionalised analogues of the in,in-[{RuII(trpy)}2(μ-bpp)(H2O)2]3+ water oxidation catalyst (bpp = bis-(2-pyridyl)pyrazolate) have been synthesised and used to create a hexametallic {Fe2Ru4} macrocycle.
Funder
European Commission
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2016/CY/C6CY01077F
Reference82 articles.
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2. Mononuclear Ruthenium–Water Oxidation Catalysts: Discerning between Electronic and Hydrogen-Bonding Effects
3. Molecular Catalysts for Water Oxidation
4. Catalytic oxidation of water by an oxo-bridged ruthenium dimer
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