Incorporation of a ruthenium–bis(pyridine)pyrazolate (Ru–bpp) water oxidation catalyst in a hexametallic macrocycle

Author:

Richmond Craig J.123,Llobet Antoni12345

Affiliation:

1. Institute of Chemical Research of Catalonia (ICIQ)

2. E-43007 Tarragona

3. Spain

4. Departament de Química

5. Universitat Autònoma de Barcelona

Abstract

New terpyridine-functionalised analogues of the in,in-[{RuII(trpy)}2(μ-bpp)(H2O)2]3+ water oxidation catalyst (bpp = bis-(2-pyridyl)pyrazolate) have been synthesised and used to create a hexametallic {Fe2Ru4} macrocycle.

Funder

European Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference82 articles.

1. L. Francàs , R.Bofill, J.García-Antón, L.Escriche, X.Sala and A.Llobet, Ru-Based Water Oxidation Catalysts in Molecular Water Oxidation Catalysis: A Key Topic for New Sustainable Energy Conversion Schemes, ed. A. Llobet, John Wiley & Sons Ltd, Chichester UK, 2014

2. Mononuclear Ruthenium–Water Oxidation Catalysts: Discerning between Electronic and Hydrogen-Bonding Effects

3. Molecular Catalysts for Water Oxidation

4. Catalytic oxidation of water by an oxo-bridged ruthenium dimer

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