Bond-bending isomerism of Au2I3−: competition between covalent bonding and aurophilicity-Reference-Cited by-同舟云学术

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Bond-bending isomerism of Au2I3−: competition between covalent bonding and aurophilicity

Published:2016 Issue:1 Volume:7 Page:475-481
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Li Wan-Lu¹²³⁴,Liu Hong-Tao⁵⁶⁷⁴,Jian Tian⁸⁹¹⁰¹¹,Lopez Gary V.⁸⁹¹⁰¹¹,Piazza Zachary A.⁸⁹¹⁰¹¹,Huang Dao-Ling⁸⁹¹⁰¹¹,Chen Teng-Teng⁸⁹¹⁰¹¹,Su Jing¹²³⁴⁵,Yang Ping¹²¹³¹⁴¹¹,Chen Xin¹²³⁴,Wang Lai-Sheng⁸⁹¹⁰¹¹,Li Jun¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry & Key Laboratory of Organic Optoelectronics and Molecular Engineering of Ministry of Education

2. Tsinghua University

3. Beijing 100084

4. China

5. Shanghai Institute of Applied Physics

6. Chinese Academy of Sciences

7. Shanghai 201800

8. Department of Chemistry

9. Brown University

10. Providence

11. USA

12. Theoretical Division T-1

13. Los Alamos National Laboratory

14. Los Alamos

Abstract

Two isomers, different only by bond angles, are discovered for Au₂I₃⁻, due to competition between aurophilic interactions and covalent bonding.

Funder

Division of Chemistry

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC03568F

Reference76 articles.

1. P. Atkin and J.de Paula, in Atkins' physical chemistry, WH Freeman and Company, 8th edn, 2006, vol. 2, pp. 362–397

2. P. Atkins , in Shriver and Atkins' inorganic chemistry, Oxford University Press, 2010, pp. 34–61

3. Bond-stretch isomerism in transition metal complexes: a reevaluation of crystallographic data

4. Bond-stretch isomerism in transition-metal complexes

5. Electronic mechanisms associated with bond-stretch isomerism in transition metal complexes

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