Asymmetric syntheses of three-membered heterocycles using chiral amide-based ammonium ylides-Reference-Cited by-同舟云学术

Asymmetric syntheses of three-membered heterocycles using chiral amide-based ammonium ylides

Published:2015 Issue:7 Volume:13 Page:2092-2099
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Pichler Mathias¹²³⁴,Novacek Johanna¹²³⁴,Robiette Raphaël⁵⁶⁷⁸,Poscher Vanessa¹²³⁴,Himmelsbach Markus⁹²³⁴,Monkowius Uwe¹⁰²³⁴,Müller Norbert¹²³⁴,Waser Mario¹²³⁴

Affiliation:

1. Institute of Organic Chemistry

2. Johannes Kepler University Linz

3. 4040 Linz

4. Austria

5. Institute of Condensed Matter and Nanosciences

6. Université catholique de Louvain

7. 1348 Louvain-la-Neuve

8. Belgium

9. Institute of Analytical Chemistry

10. Institute of Inorganic Chemistry

Abstract

Phenylglycinol serves as a powerful chiral auxiliary in ammonium ylide-mediated reactions to obtain chiral epoxides/aziridines with excellent stereoselectivities.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C4OB02318H

Reference56 articles.

1. V. K. Aggarwal , in Comprehensive Asymmetric Catalysis, ed. E. N. Jacobsen, A. Pfaltz and H. Yamamoto, Springer, New York, 1999, vol. 2, p. 679

2. Chalcogenides as Organocatalysts

3. Dimethylsulfoxonium Methylide

4. Dimethyloxosulfonium Methylide ((CH3)2SOCH2) and Dimethylsulfonium Methylide ((CH3)2SCH2). Formation and Application to Organic Synthesis

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