Rhodium-catalysed vinyl 1,4-conjugate addition coupled with Sharpless asymmetric dihydroxylation in the synthesis of the CDE ring fragment of pectenotoxin-4-Reference-Cited by-同舟云学术

Rhodium-catalysed vinyl 1,4-conjugate addition coupled with Sharpless asymmetric dihydroxylation in the synthesis of the CDE ring fragment of pectenotoxin-4

Published:2019 Issue:25 Volume:10 Page:6336-6340
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Richardson Melodie S. W.¹²³⁴⁵,Tame Christopher J.⁶⁷⁵,Poole Darren L.⁶⁷⁵,Donohoe Timothy J.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. University of Oxford

3. Chemistry Research Laboratory

4. Oxford

5. UK

6. GlaxoSmithKline Medicines Research Centre

7. Stevenage

Abstract

Rhodium and osmium catalysed C–C and C–O bond formation under mild conditions.

Funder

Engineering and Physical Sciences Research Council

AstraZeneca

Diamond Light Source

Defence Science and Technology Laboratory

GlaxoSmithKline

Novartis Pharmaceuticals UK Limited

Pfizer UK

UCB UK

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC01761E

Reference62 articles.

1. Synthetic studies towards the pectenotoxins: a review

2. Diarrhetic shellfish toxins

3. Identification and Characterization of Pectenotoxin (PTX) 4 and PTX7 as Spiroketal Stereoisomers of Two Previously Reported Pectenotoxins

4. Oocyte-based screening of cytokinesis inhibitors and identification of pectenotoxin-2 that induces Bim/Bax-mediated apoptosis in p53-deficient tumors

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