Metal-free visible-light-mediated aerobic nitrooxylation for the synthesis of nitrate esters with t-BuONO

Author:

Lv Yufen1,Hao Jindong1,Huang Jian1,Song Lianhui1,Yue Huilan2ORCID,Wei Wei1ORCID,Yi Dong3ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, Shandong, P. R. China

2. Qinghai Provincial Key Laboratory of Tibetan Medicine Research and CAS Key Laboratory of Tibetan Medicine Research, Northwest Institute of Plateau Biology, Qinghai 81000, P. R. China

3. Green Pharmaceutical Technology Key Laboratory of Luzhou City, School of Pharmacy, Southwest Medical University, Luzhou 646000, Sichuan, P. R. China

Abstract

A metal-free and sustainable visible-light-mediated method for the preparation of nitrate esters has been developed through the aerobic nitrooxylation reaction of α-diazoesters and cyclic ethers with t-BuONO in the presence of dioxygen.

Funder

Natural Science Foundation of Shandong Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

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