Temperature evolution in IR action spectroscopy experiments with sodium doped water clusters

Author:

Becker Daniel1234,Dierking Christoph W.1234,Suchan Jiří5678,Zurheide Florian1234,Lengyel Jozef910114ORCID,Fárník Michal1213148ORCID,Slavíček Petr5678ORCID,Buck Udo15164,Zeuch Thomas1234ORCID

Affiliation:

1. Universität Göttingen

2. Institut für Physikalische Chemie

3. 37077 Göttingen

4. Germany

5. Department of Physical Chemistry

6. University of Chemistry and Technology

7. 16628 Prague 6

8. Czech Republic

9. Lehrstuhl für Physikalische Chemie

10. Technische Universität München

11. Garching

12. J. Heyrovský Institute of Physical Chemistry, v.v.i.

13. Czech Academy of Sciences

14. 182 23 Prague 8

15. Max-Planck Institut für Dynamik und Selbstorganisation

16. D-37077 Göttingen

Abstract

The combination of supersonic expansions with IR action spectroscopy techniques is the basis of many successful approaches to study cluster structure and dynamics. In this paper we elucidate the temperature effect of IR excitation and evaporative cooling on sodium solvation in water clusters.

Funder

Verband der Chemischen Industrie

Grantová Agentura České Republiky

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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