Assessment of the intramolecular magnetic interactions in the highly saddled iron(iii) porphyrin π-radical cations: the change from planar to saddle conformations-Reference-Cited by-同舟云学术

Assessment of the intramolecular magnetic interactions in the highly saddled iron(iii) porphyrin π-radical cations: the change from planar to saddle conformations

Published:2019 Issue:36 Volume:48 Page:13820-13833
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Chen Ching-Chin¹²³⁴^ORCID,Wu Yi-Wen¹²³⁴,Nakamura Mikio¹⁵⁶⁷⁸,Cheng Ru-Jen¹²³⁴,Tseng Tzu-Hsien¹²³⁴,Chen Peter P.-Y.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. National Chung Hsing University

3. Taichung City 402

4. Taiwan

5. Faculty of Science

6. Toho University

7. Funabashi 274-8510

8. Japan

Abstract

The intramolecular magnetic interactions in one-electron oxidized iron(iii) porphyrin π-radical cations with planar and saddle conformations have been compared by means of a variety of spectroscopic, physical methods and unrestricted DFT calculations.

Funder

National Chung-Hsing University

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02714A

Reference53 articles.

1. Oxygen Activation and Radical Transformations in Heme Proteins and Metalloporphyrins

2. Conservation of the Conformation of the Porphyrin Macrocycle in Hemoproteins

3. M. Nakamura , Y.Ohgo and A.Ikezaki , Electronic and Magnetic Structures of Iron Porphyrin Complexes , in Handbook of Porphyrin Science , ed. K. M. Kadish , K. M. Smith and R. Guilard , World Scientific Publishing , Singapore , 2010 , vol. 7 , pp. 1–146

4. NMR studies on the electronic structure of one-electron oxidized complexes of iron(III) porphyrinates

5. High-valent iron-porphyrin complexes related to peroxidase and cytochrome P-450

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