Isotopic labelling in ethylene oligomerization: addressing the issue of 1-octene vs. 1-hexene selectivity
Author:
Affiliation:
1. Division of Chemistry and Chemical Engineering
2. California Institute of Technology
3. Pasadena
4. USA
Abstract
The selectivity-determining mechanistic steps of ethylene tetramerization and trimerization are evaluated in light of isotopic labeling experiments.
Funder
Dow Chemical Company
California Institute of Technology
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04509G
Reference42 articles.
1. Ethylene Tetramerization: A New Route to Produce 1-Octene in Exceptionally High Selectivities
2. Methylaluminoxane-Free Chromium Catalytic System for Ethylene Tetramerization
3. Monitoring Structure and Valence State of Chromium Sites during Catalyst Formation and Ethylene Oligomerization by in Situ EPR Spectroscopy
4. Formation, Operation and Deactivation of Cr Catalysts in Ethylene Tetramerization Directly Assessed by Operando EPR and XAS
5. Avoiding MAO: Alternative Activation Methods in Selective Ethylene Oligomerization
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