[Ga@Bi10(NbMes)2]3−: a linear Nb–GaI–Nb filament coordinated by a bismuth cage-Reference-Cited by-同舟云学术

[Ga@Bi₁₀(NbMes)₂]³⁻: a linear Nb–Ga^I–Nb filament coordinated by a bismuth cage

Published:2023 Issue:27 Volume:59 Page:4024-4027
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Qiao Lei¹,Yang Tao²^ORCID,Frenking Gernot³⁴^ORCID,Sun Zhong-Ming¹^ORCID

Affiliation:

1. State Key Laboratory of Element-Organic Chemistry, Tianjin Key Lab for Institution Rare Earth Materials and Applications, School of Materials Science and Engineering, Nankai University, Tianjin 300350, Tianjin, China

2. MOE Key Laboratory for Non-Equilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi’an Jiaotong University, Xi'an 710049, Shaanxi, China

3. Donostia International Physics Center (DIPC), P.K. 1072, Donostia 20080, Euskadi, Spain

4. Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse 4, Marburg 35043, Germany

Abstract

A low-valent Ga(i) complex, [Ga@Bi10(NbMes)2]3−, with a linear Nb–Ga–Nb fragment was synthesized by the reaction of K5Ga2Bi4 with NbMes2. This unusual Zintl cluster represents the first compound with Nb–Ga and Nb–Bi bonds.

Funder

Natural Science Foundation of Tianjin City

National Natural Science Foundation of China

China Postdoctoral Science Foundation

Higher Education Discipline Innovation Project

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC00631J

Reference53 articles.

1. Synthesis of a low-valent Al4+ cluster cation salt

2. Unraveling differences in aluminyl and carbene coordination chemistry: bonding in gold complexes and reactivity with carbon dioxide

3. The unique β-diketiminate ligand in aluminum(i) and gallium(i) chemistry

4. The coordination chemistry and reactivity of group 13 metal(I) heterocycles

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. [Bi₁₀{RuPPh₃}₃]⁻: Paramagnetic 13-Vertex Polybismuthide Heteroanion;Inorganic Chemistry;2024-07-16

2. Synthesis and Characterization of Homoleptic Zintl Anions [(Pn₇)M(Pn₇)]⁴⁻ (M/Pn=Pb/As, Zn/Bi);European Journal of Inorganic Chemistry;2023-09-19

3. Bismuth-Based Metal Clusters─From Molecular Aesthetics to Contemporary Materials Science;Accounts of Chemical Research;2023-04-17