Atroposelective carbonylation of aryl iodides with amides: facile synthesis of enantioenriched cyclic and acyclic amides-Reference-Cited by-同舟云学术

Atroposelective carbonylation of aryl iodides with amides: facile synthesis of enantioenriched cyclic and acyclic amides

Published:2021 Issue:21 Volume:8 Page:6067-6073
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Chen Li-Ping¹,Chen Jiang-Fei²,Zhang Yu-Jiao¹,He Xing-Yi¹,Han Ya-Fei¹,Xiao Yu-Ting¹,Lv Gui-Fen¹,Lu Xin³^ORCID,Teng Fan¹^ORCID,Sun Qing¹,Li Jin-Heng¹²^ORCID

Affiliation:

1. Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, Nanchang Hangkong University, Nanchang 330063, China

2. State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha 410082, China

3. State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

Abstract

An unprecedented palladium-catalyzed asymmetric carbonylation of ArI with carbon monoxide (CO) to expand a class of atroposelective cyclic and acyclic amides in good yields with high enantioselectivities has been reported.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangxi Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D1QO01147B

Reference55 articles.

1. Atroposelective transformation of axially chiral (hetero)biaryls. From desymmetrization to modern resolution strategies

2. Recent Advances in Catalytic Asymmetric Construction of Atropisomers