A transient lanthanum phosphinidene complex-Reference-Cited by-同舟云学术

A transient lanthanum phosphinidene complex

Published:2020 Issue:98 Volume:56 Page:15410-15413
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Watt Fabian A.¹²³^ORCID,McCabe Karl N.⁴⁵⁶,Schoch Roland¹²³^ORCID,Maron Laurent⁴⁵⁶^ORCID,Hohloch Stephan⁷⁸⁹^ORCID

Affiliation:

1. Paderborn University

2. 33098 Paderborn

3. Germany

4. Université de Toulouse

5. 31077 Toulouse

6. France

7. University of Innsbruck

8. 6020 Innsbruck

9. Austria

Abstract

Deprotonation of the terminal phosphido complex (PN)₂La(PHMes) results in the C–H-activation of one of the PN ligands via a transient phosphinidene complex.

Funder

Universität Paderborn

Universität Innsbruck

Verband der Chemischen Industrie

Daimler und Benz Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC06670B

Reference48 articles.

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2. Terminal, Anionic Carbide, Nitride, and Phosphide Transition-Metal Complexes as Synthetic Entries to Low-Coordinate Phosphorus Derivatives

3. Versatile Reactivity of a Four-Coordinate Scandium Phosphinidene Complex: Reduction, Addition, and CO Activation Reactions

4. Catalytic Reduction of Dinitrogen to Ammonia by Use of Molybdenum–Nitride Complexes Bearing a Tridentate Triphosphine as Catalysts

5. Reactions of Organic Nitriles with a Three-Coordinate Molybdenum(III) Complex and with a Related Molybdaziridine-Hydride

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