Impact of iodide ions on the speciation of radiolytic transients in molten LiCl–KCl eutectic salt mixtures

Author:

Conrad Jacy K.1ORCID,Iwamatsu Kazuhiro2ORCID,Woods Michael E.3ORCID,Gakhar Ruchi3ORCID,Layne Bobby2ORCID,Cook Andrew R.2ORCID,Horne Gregory P.1ORCID

Affiliation:

1. Center for Radiation Chemistry Research, Idaho National Laboratory, Idaho Falls, ID, P.O. Box 1625, 83415, USA

2. Department of Chemistry, Brookhaven National Laboratory, Upton, New York, 11973, USA

3. Advanced Technology of Molten Salts, Idaho National Laboratory, Idaho Falls, ID, P.O. Box 1625, 83415, USA

Abstract

A new transient interhalogen species (ICl•−) has been identified in electron pulse irradiated molten chloride salt mixtures. This species has significant implications for the transport of fission-product iodine in molten salt reactor environments.

Funder

U.S. Department of Energy

Office of Science

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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