Quantum state control on the chemical reactivity of a transition metal vanadium cation in carbon dioxide activation
Author:
Affiliation:
1. Department of Chemistry
2. University of California
3. Davis
4. USA
Abstract
By utilizing a newly developed spin-orbit electronic state selected ion source for atomic transition metal vanadium cation (V+), the chemical reactivity of V+ with CO2 has been examined in detail, indicating that the titled reaction is dominantly governed by electron spin conservation, and thus the chemical reactivity can be controlled by quantum electronic state selections.
Funder
National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP00575G
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