Magnetic transitions in exotic perovskites stabilized by chemical and physical pressure

Author:

Ma Yalin12345ORCID,Molokeev Maxim S.678910ORCID,Zhu Chuanhui12345,Zhao Shuang12345,Han Yifeng12345,Wu Meixia12345,Liu Sizhan11121314,Tyson Trevor A.11121314,Croft Mark1516171814,Li Man-Rong12345ORCID

Affiliation:

1. Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education

2. School of Chemistry

3. Sun Yat-Sen University

4. Guangzhou 510275

5. China

6. Laboratory of Crystal Physics

7. Kirensky Institute of Physics

8. Federal Research Center KSC SB RAS

9. Krasnoyarsk 660036

10. Russia

11. Department of Physics

12. New Jersey Institute of Technology

13. Newark

14. USA

15. Department of Physics & Astronomy

16. Rutgers

17. The State University of New Jersey

18. Piscataway

Abstract

Exotic perovskite Ca2−xMnxMnTaO6 (0 ≤ x ≤ 1.0) stabilized by chemical and physical pressure adopts cationic-disordered Pbnm structure and exhibits a ferromagnetic to antiferromagnetic transition around x = 0.2.

Funder

National Natural Science Foundation of China

National Science Foundation

Government Council on Grants, Russian Federation

Brookhaven National Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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