Highly enantioselective one-pot sequential synthesis of valerolactones and pyrazolones bearing all-carbon quaternary stereocentres
Author:
Affiliation:
1. Institute of Biochemistry and Molecular Biology
2. School of Life Sciences
3. Lanzhou University
4. Lanzhou 730000
5. China
Abstract
Highly enantiopure and bioactive δ-valerolactones and pyrazolones, bearing α-all-carbon quaternary stereocentres, were successfully and sequentially prepared via a one-pot procedure catalysed by a new chiral squaramide under mild reaction conditions.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/OB/D0OB02489A
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5. Acyclic Quaternary Carbon Stereocenters via Enantioselective Transition Metal Catalysis
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