Unprecedented 1,3-tert-butyl migration via the C–N single bond scission of isonitrile: an expedient metal-free route to N-sulfonyl amidines-Reference-Cited by-同舟云学术

Unprecedented 1,3-tert-butyl migration via the C–N single bond scission of isonitrile: an expedient metal-free route to N-sulfonyl amidines

Published:2020 Issue:60 Volume:56 Page:8408-8411
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Mishra Debashish¹²³⁴,Borah Arun Jyoti¹²³⁴,Phukan Pinakinee¹²³⁴,Hazarika Debojit¹²³⁴,Phukan Prodeep¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Gauhati University

3. Guwahati

4. India

Abstract

Treatment of tert-butyl isonitrile with ArSO₂NBr₂ and nitrile led to simultaneous C–N single bond scission of isonitrile and migration of tert-alkyl group to nitrogen centre of the nitrile precursor, resulting in the formation of N-sufonyl amidine.

Funder

Science and Engineering Research Board

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC02430A

Reference59 articles.

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