An approach to 7-aza-1-phosphanorbornane complexes: strain promoted rearrangement of 1-iminylphosphirane complexes and cycloaddition with olefins-Reference-Cited by-同舟云学术

An approach to 7-aza-1-phosphanorbornane complexes: strain promoted rearrangement of 1-iminylphosphirane complexes and cycloaddition with olefins

Published:2019 Issue:17 Volume:48 Page:5523-5526
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Xu Yang¹²³⁴⁵,Wang Min¹²³⁴⁵,Wei Donghui¹²³⁴⁵^ORCID,Tian Rongqiang¹²³⁴⁵^ORCID,Duan Zheng¹²³⁴⁵^ORCID,Mathey François¹²³⁴⁵^ORCID

Affiliation:

1. College of Chemistry and Molecular Engineering

2. International Phosphorus Laboratory

3. International Joint Research Laboratory for Functional Organophosphorus Materials of Henan Province

4. Zhengzhou University

5. Zhengzhou 450001

Abstract

1-Iminylphosphirane W(CO)₅ complexes react with alkenes to form the original 7-aza-1-phosphanorbornane complexes. The mechanism including the rearrangement of phosphirane into a dipolar five-membered ring and the following cycloaddition of this dipolar intermediate with alkenes.

Funder

National Natural Science Foundation of China

China Postdoctoral Science Foundation

Zhengzhou University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00838A

Reference28 articles.

1. Cyclopropanation Strategies in Recent Total Syntheses