Thermo-responsive emission induced by different delocalized excited-states in isomorphous Pd(<scp>ii</scp>) and Pt(<scp>ii</scp>) one-dimensional chains-Reference-Cited by-同舟云学术

Thermo-responsive emission induced by different delocalized excited-states in isomorphous Pd(ii) and Pt(ii) one-dimensional chains

Published:2024 Issue:35 Volume:15 Page:14497-14505
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Saito Tomoya¹,Yoshida Masaki²^ORCID,Segawa Kaito²,Saito Daisuke¹²^ORCID,Takayama Junichi³^ORCID,Hiura Satoshi³^ORCID,Murayama Akihiro³^ORCID,Lakshan Nishshanka M.⁴,Sameera W. M. C.⁴⁵^ORCID,Kobayashi Atsushi¹^ORCID,Kato Masako²^ORCID

Affiliation:

1. Department of Chemistry, Faculty of Science, Hokkaido University, North-10 West-8, Kita-ku, Sapporo, Hokkaido 060-0810, Japan

2. Department of Applied Chemistry for Environment, School of Biological and Environmental Sciences, Kwansei Gakuin University, 1 Gakuen-Uegahara, Sanda, Hyogo 669-1330, Japan

3. Faculty of Information Science and Technology, Hokkaido University, North-14 West-9, Kita-ku, Sapporo, Hokkaido 060-0814, Japan

4. Department of Chemistry, University of Colombo, Kumaratunga Munidasa Mawatha, Colombo 00700, Sri Lanka

5. Department of Chemistry and Molecular Biology, University of Gothenburg, SE-41390 Gothenburg, Sweden

Abstract

The emissions of isomorphous Pt(ii) and Pd(ii) one-dimensional chains exhibited distinct thermal responses, revealing the limiting factor for extending the excited-state delocalization across multiple molecules through metallophilic interactions.

Funder

Japan Society for the Promotion of Science

Hyogo Science and Technology Association

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC04497E

Reference79 articles.

1. On the Bonding Nature of the M.cntdot. .cntdot. .cntdot.M Interactions in Dimers of Square-Planar Pt(II) and Rh(I) Complexes

2. Strong Closed-Shell Interactions in Inorganic Chemistry

3. A trinuclear Pt(ii) compound with short Pt–Pt–Pt contacts. An analysis of the influence of π–π stacking interactions on the strength and length of the Pt–Pt bond

4. The Energetic Significance of Metallophilic Interactions

5. A briefing on aurophilicity