The simplest Diels–Alder reactions are not endo-selective
Author:
Affiliation:
1. Research School of Chemistry
2. Australian National University
3. Canberra
4. Australia
5. School of Chemistry
6. University of New South Wales
Abstract
Cycloadditions of deuterium-labeled 1,3-butadiene with monosubstituted alkenic dienophiles challenge the widespread assumption of endo-selectivity in prototypical Diels–Alder reactions.
Funder
Australian Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC04553E
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