Thermodynamics of spin crossover in a bis(terpyridine) cobalt(<scp>ii</scp>) complex featuring a thioether functionality-Reference-Cited by-同舟云学术

Thermodynamics of spin crossover in a bis(terpyridine) cobalt(ii) complex featuring a thioether functionality

Published:2024 Issue:23 Volume:53 Page:9933-9941
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ferraz Lobato Lúcio¹^ORCID,Ciattini Samuele²,Gallo Angelo³^ORCID,Allão Cassaro Rafael A.¹^ORCID,Sorace Lorenzo⁴^ORCID,Poneti Giordano¹⁵^ORCID

Affiliation:

1. Instituto de Química, Universidade Federal do Rio de Janeiro, Rio de Janeiro, RJ, 21941-909, Brazil

2. Interdepartmental Center for Crystallography (CRIST), University of Florence, Via della Lastruccia 3–13, 50019 Sesto Fiorentino, Italy

3. Department of Chemistry, University of Turin, Via Pietro Giuria 7, 10125 Torino, Italy

4. Department of Chemistry “U. Schiff” and INSTM Research Unit, University of Florence, Via della Lastruccia 3–13, 50019 Sesto Fiorentino, Italy

5. Dipartimento di Scienze Ecologiche e Biologiche, Università degli Studi della Tuscia, Largo dell'Università, 01100, Viterbo, Italy

Abstract

A new cobalt(ii) complex featuring a terpyridine ligand functionalized with a thioether group has been prepared, structurally and magnetically characterized, and the thermodynamics of its spin crossover behaviour investigated in solution.

Funder

Fundação Carlos Chagas Filho de Amparo à Pesquisa do Estado do Rio de Janeiro

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Ministero dell'Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00574K

Reference73 articles.

1. Dynamic molecular crystals with switchable physical properties

2. Spin crossover iron(ii) complexes as PARACEST MRI thermometers

3. Molecular actuators driven by cooperative spin-state switching

4. Robust spin crossover and memristance across a single molecule

5. The molecular way

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