Synthesis, structure, and alkyne insertion of a mixed-sandwich zirconacarborane alkyl-Reference-Cited by-同舟云学术

Synthesis, structure, and alkyne insertion of a mixed-sandwich zirconacarborane alkyl

Published:2015 Issue:5 Volume:2 Page:467-472
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Liu Dongmei¹²³⁴⁵,Qiu Zaozao⁶⁷⁸⁹⁵,Xie Zuowei¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Center of Novel Functional Materials and State Key Laboratory of Synthetic Chemistry

3. The Chinese University of Hong Kong

4. Shatin, New Territories

5. China

6. Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis

7. Shanghai Institute of Organic Chemistry

8. Chinese Academy of Sciences

9. Shanghai 200032

Abstract

A neutral mixed-sandwich zirconacarborane alkyl reacts with both internal and terminal alkynes to give the Zr–C σ bond mono-insertion products, in which both electronic and steric factors play a role in the regioselectivity.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/QI/C4QI00244J

Reference76 articles.

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