Cleaner technology for the production of linear long-chain α-olefins through a “millisecond” oxidative cracking process: a positive impact of the reactant carbon chain length

Author:

Cruchade Hugo1,Pouilloux Y.1,Beauchet R.1,Pinard Ludovic1ORCID

Affiliation:

1. Institut de Chimie des Milieux et Matériaux de Poitiers (IC2MP), UMR 7285 CNRS, 4 rue Michel Brunet, Bâtiment B27, TSA 51106, 86073 Poitiers Cedex 9, France

Abstract

The oxidative cracking of n-decane, n-dodecane, n-tetradecane and n-hexadecane was assessed at millisecond contact times on a platinum catalyst at a C/O molar ratio of 1.8.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference40 articles.

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2. Olefins from conventional and heavy feedstocks: Energy use in steam cracking and alternative processes

3. G. R.Lappin , L. H.Nemec , J. D.Sauer and J. D.Wagner , Kirk-Othmer Encyclopedia of Chemical Technology , American Cancer Society , 2010 , pp. 1–20

4. Oligomerization of .alpha.-olefins to higher oligomers

5. Selective Ethylene Oligomerization

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