Suppression of near band edge emission in specially engineered ZnO twin nanorods

Author:

Singh Avanendra12345,Senapati Kartik12345,Satpati Biswarup6785ORCID,Sahoo Pratap K.12345ORCID

Affiliation:

1. School of Physical Sciences

2. National Institute of Science Education and Research (NISER)

3. HBNI

4. Jatni (Bhubaneswar)

5. India

6. Surface Physics and Material Science Division

7. Saha Institute of Nuclear Physics

8. Kolkata

Abstract

Twin crystalline ZnO nanorods with tunable amorphous joints are synthesized via a hydrothermal route. We find a strong coupling of acoustic phonon modes to free excitons in these structures. As a result, significant non-radiative transfer of carriers from the conduction band to defect bands occurs, leading to a loss of the near band edge emission intensity below ∼180 K.

Funder

Department of Atomic Energy, Government of India

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference52 articles.

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4. Zinc Oxide Bulk, Thin Films, and Nanostructures, ed. C. Jagadish and S. J. Pearton, Elsevier, New York, 2006

5. The exciton spectrum of zinc oxide

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