Mechanistic insights can resolve the low reactivity and selectivity issues in intermolecular Rauhut–Currier (RC) reaction of γ-hydroxyenone
Author:
Affiliation:
1. Department of Chemistry
2. Korea Advanced Institute of Science and Technology (KAIST)
3. Daejeon 34141
4. Republic of Korea
5. St. Berchmans College (Autonomous)
6. Changanassery
7. India
Abstract
Low reactivity of Rauhut–Currier reaction can be resolved by shifting the equilibrium of the enone/enolate of the substrate towards enolate.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2020/NJ/D0NJ02732D
Reference49 articles.
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4. Aza-Morita−Baylis−Hillman Reactions and Cyclizations of Conjugated Dienes Activated by Sulfone, Ester, and Keto Groups
5. Influence of Michael Acceptor Stereochemistry on Intramolecular Morita−Baylis−Hillman Reactions
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