Tracking accelerated oxygen evolution reaction enabled by explosive reconstruction of active species based on CoxN@NC

Author:

Choi Hyung Wook1,Kim Jiwon2,Bang Hyeon-Seok234,Badawy Khaled5,Lee Ui Young2,Jeong Dong In2,Kim Yeseul2,Hamad Kotiba2,Kang Bong Kyun6,Weon Byung Mook2,Oh Hyung-Suk34ORCID,Singh Nirpendra7ORCID,Yoon Dae Ho12ORCID

Affiliation:

1. SKKU Advanced Institute of Nano Technology (SAINT), Sungkyunkwan University, Suwon 16419, Republic of Korea

2. School of Advanced Materials Science and Engineering, Sungkyunkwan University, 2066, Seobu-ro, Jangan-gu, Suwon-si, Gyeonggi-do, 16419, Republic of Korea

3. Clean Energy Research Center, Korea Institute of Science and Technology (KIST), Hwarang-ro 14-gil 5, Seongbuk-gu, Seoul 02792, Republic of Korea

4. KIST-SKKU Carbon-Neutral Research Center, Sungkyunkwan University (SKKU), Suwon 16419, Republic of Korea

5. Mechanical Engineering Department, Khalifa University of Science and Technology, Abu Dhabi-127788, UAE

6. Department of Electronic Materials, Devices, and Equipment Engineering, Soonchunhyang University, 22, Soonchunhyang-ro, Asan City, Chungnam, 31538, Republic of Korea

7. Department of Physics, Khalifa University of Science and Technology, Abu Dhabi-127788, UAE

Abstract

The development of a hierarchical structure of Co/Co4N@NC has been successfully achieved. The robust oxygen evolution reaction activity of Co/Co4N@NC is attributed to the modulation of the d-band center, which reconstruct Co2+ into Co3+.

Funder

National Research Foundation of Korea

Korea Basic Science Institute

Ministry of Science and ICT, South Korea

Publisher

Royal Society of Chemistry (RSC)

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