Synthesis and structural, photophysical, electrochemical redox and axial ligation properties of highly electron deficient perchlorometalloporphyrins and selective CN− sensing by Co(ii) complexes-Reference-Cited by-同舟云学术

Synthesis and structural, photophysical, electrochemical redox and axial ligation properties of highly electron deficient perchlorometalloporphyrins and selective CN− sensing by Co(ii) complexes

Published:2018 Issue:10 Volume:42 Page:8190-8199
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Chaudhri Nivedita¹²³⁴,Butcher Ray J.¹⁵⁶⁷,Sankar Muniappan¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Roorkee

3. Roorkee 247667

4. India

5. Howard University

6. Washington

7. USA

Abstract

Synthesis and characterization of MTPP(NO₂)Cl₇ have been reported. Zn^II porphyrins exhibited higher Lewis acidity as compared to perbromoporphyrins. Co^II porphyrins were utilized for the selective rapid visual detection of cyanide ions.

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C7NJ04418F

Reference84 articles.

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4. R. H. Felton , in The Porphyrins , ed. D. Dolphin , Academic Press , New York , 1978 , vol. 5, p. 127

5. Nonplanar distortion modes for highly substituted porphyrins

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