Conformational analysis of triphenylphosphine ligands in stereogenic monometallic complexes: tools for predicting the preferred configuration of the triphenylphosphine rotor-Reference-Cited by-同舟云学术

Conformational analysis of triphenylphosphine ligands in stereogenic monometallic complexes: tools for predicting the preferred configuration of the triphenylphosphine rotor

Published:2015 Issue:12 Volume:44 Page:5451-5466
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Costello James F.¹²³⁴,Davies Stephen G.⁵⁶⁷⁸⁴,Gould Elliott T. F.¹²³⁴,Thomson James E.⁵⁶⁷⁸⁴

Affiliation:

1. Faculty of Applied Sciences

2. University of the West of England

3. Bristol

4. UK

5. Department of Chemistry

6. Chemistry Research Laboratory

7. University of Oxford

8. Oxford

Abstract

A model has been developed to reliably predict the configuration of the triphenylphosphine rotor of stereogenic metal complexes [M(η⁵-C₅H₅)(PPh₃)(L¹)(L²)].

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00250H

Reference47 articles.

1. Chiral properties of tetrathiatriarylmethyl spin probes

2. Molecular Propellers that Consist of Dehydrobenzo[14]annulene Blades

3. An enantiopure pseudo-C3-symmetric titanium triflate with propeller-like chirality as a catalyst for asymmetric sulfoxidation reactions

4. Triarylmethanols with Bulky Aryl Groups and the NOESY/EXSY Experimental Observation of a Two-Ring-Flip Mechanism for the Helicity Reversal of Molecular Propellers

5. Chiroptical molecular propellers based on hexakis(phenylethynyl)benzene through the complexation-induced intramolecular transmission of local point chirality

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