Highly selective acid-catalyzed olefin isomerization of limonene to terpinolene by kinetic suppression of overreactions in a confined space of porous metal–macrocycle frameworks-Reference-Cited by-同舟云学术

Highly selective acid-catalyzed olefin isomerization of limonene to terpinolene by kinetic suppression of overreactions in a confined space of porous metal–macrocycle frameworks

Published:2022 Issue:30 Volume:13 Page:8752-8758
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

He Wei¹^ORCID,Tashiro Shohei¹^ORCID,Shionoya Mitsuhiko¹^ORCID

Affiliation:

1. Department of Chemistry, Graduate School of Science, The University of Tokyo, Tokyo 113-0033, Japan

Abstract

A porous metal–macrocycle framework (MMF) equipped with a Brønsted acid catalyst in nanochannels enables highly selective isomerization of limonene to terpinolene by kinetically suppressing over-isomerization at confined acid sites.

Funder

Japan Society for the Promotion of Science

Iketani Science and Technology Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC01561G

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