An nπ* gated decay mediates excited-state lifetimes of isolated azaindoles-Reference-Cited by-同舟云学术

An nπ* gated decay mediates excited-state lifetimes of isolated azaindoles

Published:2020 Issue:33 Volume:22 Page:18639-18645
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Lamas Iker¹²³⁴⁵^ORCID,Montero Raúl⁶⁷⁸⁹⁵^ORCID,Martínez-Martínez Virginia¹²³⁴⁵^ORCID,Longarte Asier¹²³⁴⁵^ORCID,Blancafort Lluís¹⁰¹¹¹²¹³⁵^ORCID

Affiliation:

1. Departamento de Química Física

2. Universidad del País Vasco (UPV/EHU)

3. Apart. 644

4. 48080 Bilbao

5. Spain

6. SGIker Laser Facility

7. UPV/EHU

8. Sarriena, s/n

9. 48940 Leioa

10. Institut de Química Computacional i Catàlisi and Departament de Química

11. Universitat de Girona

12. C/M.A. Capmany 69

13. 17003 Girona

Abstract

The excited-state lifetime of 5- and 6-azaindole (AI) is 100–800 fs, and that of the 7-AI isomer several orders of magnitude slower. The three molecules have a similar decay mechanism, and the difference lies in the relative energy of the nπ* state.

Funder

Secretaría de Estado de Investigación, Desarrollo e Innovación

Ministerio de Ciencia e Innovación

Ekonomiaren Garapen eta Lehiakortasun Saila, Eusko Jaurlaritza

Euskal Herriko Unibertsitatea

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP02635B

Reference39 articles.