Bis(chalcogenones) as pincer ligands: isolation and Heck activity of the selone-ligated unsymmetrical C,C,Se–Pd pincer complex-Reference-Cited by-同舟云学术

Bis(chalcogenones) as pincer ligands: isolation and Heck activity of the selone-ligated unsymmetrical C,C,Se–Pd pincer complex

Published:2015 Issue:26 Volume:44 Page:11893-11900
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ghavale Ninad¹²³⁴,Manjare Sudesh T.¹²³⁴¹,Singh Harkesh B.¹²³⁴,Butcher Ray J.¹⁵⁶⁷

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Bombay

3. Mumbai 400076

4. India

5. Howard University

6. Washington, D. C. 20059

7. USA

Abstract

The reaction of meta-phenylene-bis(1-methyl-1H-imidazole-2(3H)-selone) with [Pd₂(μ-Cl)₂(2-C₆H₄CH₂NMe₂)₂] in dry benzene and glacial acetic acid resulted in the formation of an unsymmetrical 5,6-membered C,C,Se–Pd(ii) pincer complex.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01565K

Reference38 articles.

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2. G. van Koten and R. J. M. K.Gebbink

3. G. van Koten and D.Milstein

4. S. Humphrey

5. The Coordination Chemistry of Pentafluorophenylphosphino Pincer Ligands to Platinum and Palladium

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