Structural, optical, dielectric and electrical transport properties of a [Mg(H2O)6]2+-templated proton conducting, semiconducting and photoresponsive 3D hydrogen bonded supramolecular framework

Author:

Singha Soumen1,Khanra Bhaskar1,Goswami Somen1,Mondal Rituparna2,Jana Rajkumar13,Dey Arka1ORCID,Dey Sanjoy Kumar4,Ray Partha Pratim1,Rizzoli Corrado5,Saha Rajat6ORCID,Kumar Sanjay1ORCID

Affiliation:

1. Department of Physics, Jadavpur University, Jadavpur, Kolkata-700032, WB, India

2. Department of Electronics, Barrackpore Rastraguru Surendranath College, Barrackpore, West Bengal 700120, India

3. Department of Physics, Techno India University, EM-4, Sector-V, Salt lake, Kolkata-700091, India

4. Purulia Polytechnic, Vivekananda Nagar, Purulia, 723147, WB, India

5. Dipartimento SCVSA, Università di Parma, Parco Area delle Scienze 17/A, Parma, Italy

6. Department of Chemistry, Kazi Nazrul University, Asansol-713340, WB, India

Abstract

{[Co(2,5-Pdc)2,(H2O)2]2−·[Mg(H2O)6]2+·4(H2O)} (where 2,5-pdc = 2,5-pyridinedicarboxylate): a proton conducting semiconducting photoresponsive [Mg(H2O)6]2+ templated 3D hydrogen bonded supramolecular framework (HSF).

Funder

University Grants Commission

Jadavpur University

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference99 articles.

1. Transport in Proton Conductors for Fuel-Cell Applications:  Simulations, Elementary Reactions, and Phenomenology

2. Recent Development of Polymer Electrolyte Membranes for Fuel Cells

3. P.Colomban , in Proton Conductors: Solids , Membranes and GelsMaterials and Devices , ed. Baxter, H. , Vol. 2, Cambridge University Press , Cambridge , 1992

4. Review of Advanced Materials for Proton Exchange Membrane Fuel Cells

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