Facile ring-opening of THF at a lithium center induced by a pendant Si–H bond and BPh3-Reference-Cited by-同舟云学术

Facile ring-opening of THF at a lithium center induced by a pendant Si–H bond and BPh3

Published:2017 Issue:25 Volume:46 Page:8017-8021
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mukherjee Debabrata¹²³⁴^ORCID,Osseili Hassan¹²³⁴,Spaniol Thomas P.¹²³⁴^ORCID,Okuda Jun¹²³⁴^ORCID

Affiliation:

1. Institute of Inorganic Chemistry

2. RWTH Aachen University

3. 52056 Aachen

4. Germany

Abstract

Triphenylborane (BPh₃) induces a facile THF ring-opening at a lithium center where a pendant Si–H bond acts as the nucleophile to cleave the C_α–O bond.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01671A

Reference64 articles.

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2. Tetrahydrofuran Ring Opening with Acid Chlorides Catalyzed by Samarium Triiodides

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4. Tetrahydrofuran Ring Opening with Acyloxyphosphonium Bromide Catalysed by Allylsamarium Bromide: A Novel and Effective Method for the Preparation of 4-Bromobutyl Esters

5. Cooperative THF Ring‐Opening by B(C 6 F 5 ) 3 and a Tellurium Diimide Dimer

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