A microporous anionic metal–organic framework for aqueous encapsulation and highly reversible sensitization of light-emitting Tb3+ ions

Author:

Jin J. C.12,Liu X. Y.13ORCID,Yang G. P.1,Hou L.1ORCID,Wang Y. Y.1ORCID

Affiliation:

1. Address Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University, Xi’an 710069, P. R. China

2. Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology, West Anhui University, Anhui 237012, P. R. China

3. State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, Ningxia University, Yinchuan 750021, P. R. China

Abstract

An anionic porous material can serve as both a host and an antenna for protecting and sensitizing extra-framework light-emitting Eu3+/Tb3+ ions. The Tb3+ uptake and release is a reversible process and the cationic Tb3+ can be gradually released.

Funder

Natural Science Foundation of Anhui Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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