E–Z isomerization in Suzuki cross-couplings of haloenones: ligand effects and evidence for a separate catalytic cycle-Reference-Cited by-同舟云学术

E–Z isomerization in Suzuki cross-couplings of haloenones: ligand effects and evidence for a separate catalytic cycle

Published:2018 Issue:7 Volume:16 Page:1134-1143
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Chehal Navneet K.¹²³⁴,Budzelaar Peter H. M.¹²³⁴⁵,Hultin Philip G.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Manitoba

3. Winnipeg

4. Canada R3T 2N2

5. Dipartimento di Scienze Chimiche

Abstract

We present evidence for a palladocyclic enolate-like pathway for isomerization of enones occurring during Suzuki cross-coupling reactions.

Funder

University of Manitoba

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/OB/C7OB02925J

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