Cobalt-catalyzed enantioselective desymmetrizing reductive cyclization of alkynyl cyclodiketones-Reference-Cited by-同舟云学术

Cobalt-catalyzed enantioselective desymmetrizing reductive cyclization of alkynyl cyclodiketones

Published:2023 Issue:23 Volume:14 Page:6393-6398
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Liang Ren-Xiao¹^ORCID,Tang Heng-Wei¹,Liu Jia-Liang¹,Xu Jian-Feng¹,Chen Ling-Jia¹,Jia Yi-Xia¹²^ORCID

Affiliation:

1. College of Chemical Engineering, State Key Laboratory Breeding Base of Green-Chemical Synthesis Technology, Zhejiang University of Technology, Chaowang Road 18#, Hangzhou 310014, China

2. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. China

Abstract

A highly enantioselective cobalt-catalyzed desymmetrizing reductive cyclization of alkynyl cyclodiketones has been developed by employing HBpin as a reducing agent and ferrocene-based PHOX as a chiral ligand.

Funder

Natural Science Foundation of Zhejiang Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC00119A

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